Design and synthesis of 2,3,4,9-tetrahydro-1H-carbazole and 1,2,3,4-tetrahydro-cyclopenta[b]indole derivatives as non-nucleoside inhibitors of hepatitis C virus NS5B RNA-dependent RNA polymerase

Bioorg Med Chem Lett. 2006 May 1;16(9):2532-4. doi: 10.1016/j.bmcl.2006.01.105. Epub 2006 Feb 15.

Abstract

A novel class of HCV NS5B RNA dependent RNA polymerase inhibitors containing 2,3,4,9-tetrahydro-1H-carbazole and 1,2,3,4-tetrahydro-cyclopenta[b]indole scaffolds were designed and synthesized. Optimization of the aromatic region showed preference for 5,8-disubstitution pattern in both the scaffolds examined while favoring the n-propyl moiety for the C-1 position. 1,2,3,4-tetrahydro-cyclopenta[b]indole scaffold was slightly more potent than the corresponding 2,3,4,9-tetrahydro-1H-carbazole and analogue 36 displayed an IC50 of 550 nM against HCV NS5B enzyme.

MeSH terms

  • Antiviral Agents / chemical synthesis*
  • Antiviral Agents / chemistry
  • Antiviral Agents / pharmacology
  • Carbazoles* / chemical synthesis
  • Carbazoles* / chemistry
  • Carbazoles* / pharmacology
  • Cyclopentanes* / chemical synthesis
  • Cyclopentanes* / chemistry
  • Cyclopentanes* / pharmacology
  • Drug Design
  • Indoles* / chemical synthesis
  • Indoles* / chemistry
  • Indoles* / pharmacology
  • Microbial Sensitivity Tests
  • Molecular Structure
  • RNA-Dependent RNA Polymerase / antagonists & inhibitors*
  • Reverse Transcriptase Inhibitors / chemical synthesis*
  • Reverse Transcriptase Inhibitors / chemistry
  • Reverse Transcriptase Inhibitors / pharmacology
  • Structure-Activity Relationship
  • Viral Nonstructural Proteins / drug effects*

Substances

  • 1,2,3,4-tetrahydro-cyclopenta(b)indole
  • 2,3,4,9-tetrahydro-1H-carbazole
  • Antiviral Agents
  • Carbazoles
  • Cyclopentanes
  • Indoles
  • Reverse Transcriptase Inhibitors
  • Viral Nonstructural Proteins
  • NS-5 protein, hepatitis C virus
  • RNA-Dependent RNA Polymerase