Self-assembly of supramolecular platinum complexes with bis-4-pyridyl cavitands

J Org Chem. 2006 May 26;71(11):4155-63. doi: 10.1021/jo060133o.

Abstract

The design and self-assembly of six new supramolecular complexes (four triangles and two 2+2 assemblies) are described. These assemblies incorporate two new bispyridyl cavitand building blocks and were prepared in excellent yields (85-95%). The assemblies and building blocks were characterized with multinuclear NMR spectroscopy, electrospray ionization mass spectrometry, and elemental analysis. Isotopically resolved mass spectrometry along with NMR data confirms the existence of the six assemblies.

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Ethers, Cyclic / chemistry*
  • Molecular Structure
  • Platinum / chemistry*

Substances

  • Ethers, Cyclic
  • Platinum