Stokes-Einstein relation in supercooled aqueous solutions of glycerol

Phys Rev Lett. 2006 Apr 14;96(14):145502. doi: 10.1103/PhysRevLett.96.145502. Epub 2006 Apr 11.

Abstract

The diffusion of glycerol molecules decreases with decreasing temperature as its viscosity increases in a manner simply described by the Stokes-Einstein relation. Approaching the glass transition, this relation breaks down as it does with a number of other pure liquid glass formers. We have measured the diffusion coefficient for binary mixtures of glycerol and water and find that the Stokes-Einstein relation is restored with increasing water concentration. Our comparison with theory suggests that adding water postpones the formation of frustration domains.