Direct orthoruthenation of planar prochiral pyridine derivatives by C-H bond activation with [Ru(CO)2Cl2]n and its unexpected stereoselectivity

Akram Hijazi; Jean-Pierre Djukic; Michel Pfeffer; Louis Ricard; Nathalie Kyritsakas-Gruber; Jesus Raya; Philippe Bertani; André de Cian

doi:10.1021/ic0604112

Direct orthoruthenation of planar prochiral pyridine derivatives by C-H bond activation with [Ru(CO)2Cl2]n and its unexpected stereoselectivity

Inorg Chem. 2006 Jun 12;45(12):4589-91. doi: 10.1021/ic0604112.

Authors

Akram Hijazi¹, Jean-Pierre Djukic, Michel Pfeffer, Louis Ricard, Nathalie Kyritsakas-Gruber, Jesus Raya, Philippe Bertani, André de Cian

Affiliation

¹ Institut de Chimie de Strasbourg, CNRS LC3 UMR 7177, Université Louis Pasteur, 67000 Strasbourg, France.

PMID: 16749820
DOI: 10.1021/ic0604112

Abstract

The treatment of planar prochiral pyridine derivatives with d6 [Ru(CO)2Cl2]n stereoselectively and efficiently produces new dimeric ortho-ruthenated complexes.