Abstract
The reaction of a nickelalactone with dppm, resulting in the formation of a stable binuclear Ni(I) complex with an acrylate, a Ph2P- and a dppm bridge, models a key step in the formation of acrylic acid from CO2 and ethylene.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Acrylates / chemical synthesis*
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Acrylates / chemistry
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Carbon Dioxide / chemistry*
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Catalysis
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Crystallography, X-Ray
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Ethylenes / chemistry*
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Ligands
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Models, Molecular
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Molecular Structure
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Nickel / chemistry*
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Organometallic Compounds / chemistry*
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Stereoisomerism
Substances
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Acrylates
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Ethylenes
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Ligands
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Organometallic Compounds
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Carbon Dioxide
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Nickel
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ethylene
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acrylic acid