Abstract
A novel spin transition between S = 5/2 and S = 3/2 has been observed for the first time in five-coordinate, highly saddled iron(III) porphyrinates by EPR and SQUID measurements at extremely low temperatures.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Cold Temperature*
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Electron Spin Resonance Spectroscopy
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Hemin / chemistry*
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Magnetics
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Models, Molecular
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Molecular Structure
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Sulfur / chemistry*