Voltammetric behavior and determination of 17 beta-estradiol at multi-wall carbon nanotube-Nafion modified glassy carbon electrode

Anal Sci. 2006 Jun;22(6):895-8. doi: 10.2116/analsci.22.895.

Abstract

For the purpose of low cost and sensitive electrochemical detection of 17 beta-estradiol (E2), a multi-wall carbon nanotube (MWNT)-Nafion modified electrode was fabricated. The MWNT modified electrode shows enhancement for the anodic peak current of E2 compared with the value obtained using a bare electrode. The anodic peak current measured by square wave voltammetry after 5 min open-circuit accumulation was proportional to the concentration of E2 over the range of 2.5 x 10(-7) to 10 10(-6) M, and a detection limit of 1 x 10(-8) M was obtained.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Biosensing Techniques*
  • Carbon / chemistry*
  • Chemistry Techniques, Analytical / instrumentation
  • Chemistry Techniques, Analytical / methods*
  • Electric Conductivity
  • Electrochemistry / instrumentation
  • Electrochemistry / methods*
  • Electrodes*
  • Estradiol / analysis*
  • Estradiol / chemistry
  • Fluorocarbon Polymers / chemistry*
  • Hydrogen-Ion Concentration
  • Microelectrodes
  • Oxygen / metabolism
  • Sensitivity and Specificity
  • Solutions
  • Time Factors

Substances

  • Fluorocarbon Polymers
  • Solutions
  • perfluorosulfonic acid
  • Estradiol
  • Carbon
  • Oxygen