The effect of holes buffer layer PEDOT doped with one-dimensional nanomaterials on the performance of polymer light-emitting diodes was investigated. The photoluminescence efficiency of double layer sample PEDOT/MEH-PPV was enhanced by doping one-dimensional nanomaterials (TiO2 nanotube and ZnO nanorod) into PEDOT layer. Stronger interaction of one-dimensional nanomaterials and PEDOT suppressed the creation of defect states which can quench radiative recombination of excitons. The electroluminescence efficiency of device was improved by 2 and 2.5 folds by doping TiO2 nanotubes and ZnO nanorods into holes buffer layer PEDOT respectively.