Abstract
Solid tumours contain regions of very low oxygen concentrations that are said to be hypoxic. Hypoxia is a natural phenotype of solid tumours resulting from an imperfect vascular network. There are a number of consequences associated with tumour hypoxia including: resistance to ionising radiation, resistance to chemotherapy and the magnification of mutated p53. In addition tissue hypoxia has been regarded as a key factor for tumour aggressiveness and metastasis by activation of signal transduction pathways and gene regulatory mechanisms. It is clear that hypoxia in solid tumours promotes a strong oncogenic phenotype and is a phenomenon that occurs in all solid tumours. As such this provides a significant target for drug discovery particularly for tumour-targeting agents. A range of chemical classes (N-oxides, quinones, nitro-aromatics) have been explored as bioreductive agents that target tumour hypoxia. The most advanced agent, tirapazamine, is in phase III clinical trials in combination with cis-platin. The aim of this review is to give a brief overview of the current molecules and strategies being explored for targeting tumour hypoxia.
MeSH terms
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Anthraquinones / pharmacokinetics
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Anthraquinones / therapeutic use
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Antineoplastic Agents / pharmacokinetics
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Antineoplastic Agents / therapeutic use*
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Aziridines / pharmacokinetics
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Aziridines / therapeutic use
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Benzoquinones / pharmacokinetics
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Benzoquinones / therapeutic use
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Cell Hypoxia / drug effects*
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Clinical Trials, Phase III as Topic
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Drug Screening Assays, Antitumor
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Humans
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Imidazoles / pharmacokinetics
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Imidazoles / therapeutic use
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Indolequinones / pharmacokinetics
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Indolequinones / therapeutic use
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Neoplasms / blood supply
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Neoplasms / drug therapy*
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Neoplasms / metabolism
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Prodrugs / pharmacokinetics
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Prodrugs / therapeutic use
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Quinolines / pharmacokinetics
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Quinolines / therapeutic use
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Radiation-Sensitizing Agents / pharmacokinetics
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Radiation-Sensitizing Agents / therapeutic use*
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Tirapazamine
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Triazines / pharmacokinetics
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Triazines / therapeutic use
Substances
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2,5-diaziridinyl-3-(hydroxymethyl)-6-methyl-1,4-benzoquinone
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4-(3-(2-nitro-1-imidazolyl)-propylamino)-7-chloroquinoline hydrochloride
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Anthraquinones
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Antineoplastic Agents
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Aziridines
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Benzoquinones
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Imidazoles
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Indolequinones
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Prodrugs
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Quinolines
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Radiation-Sensitizing Agents
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Triazines
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Tirapazamine
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AQ4N
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tretazicar
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apaziquone