Field-induced CO adsorption and formation of carbonyl waves on gold nanotips

J Chem Phys. 2006 Aug 7;125(5):054704. doi: 10.1063/1.2227397.

Abstract

We report a study of the adsorption and reaction of CO on a gold nanotip in high electrostatic fields. Field ion microscopy is used to investigate the emergence of a Au-carbonyl wave that is made visible with oxygen as the imaging gas. We set up a simple kinetic model that reproduces the adsorption wave and confirms that the presence of oxygen merely serves as an imaging gas and does not lead to field-induced oxidation of CO.