A synthetic congener modeled on a microbicidal domain of thrombin- induced platelet microbicidal protein 1 recapitulates staphylocidal mechanisms of the native molecule

Antimicrob Agents Chemother. 2006 Nov;50(11):3786-92. doi: 10.1128/AAC.00038-06. Epub 2006 Sep 5.

Abstract

Thrombin-induced platelet microbicidal protein 1 (tPMP-1) is a staphylocidal peptide released by activated platelets. This peptide initiates its microbicidal activity by membrane permeabilization, with ensuing inhibition of intracellular macromolecular synthesis. RP-1 is a synthetic congener modeled on the C-terminal microbicidal alpha-helix of tPMP-1. This study compared the staphylocidal mechanisms of RP-1 with those of tPMP-1, focusing on isogenic tPMP-1-susceptible (ISP479C) and -resistant (ISP479R) Staphylococcus aureus strains for the following quantitative evaluations: staphylocidal efficacy; comparative MIC; membrane permeabilization (MP) and depolarization; and DNA, RNA, and protein synthesis. Although the proteins had similar MICs, RP-1 caused significant killing of ISP479C (<50% survival), correlating with extensive MP (>95%) and inhibition of DNA and RNA synthesis (>90%), versus substantially reduced killing of ISP479R (>80% survival), with less MP (55%) and less inhibition of DNA or RNA synthesis (70 to 80%). Interestingly, RP-1-induced protein synthesis inhibition was equivalent in both strains. RP-1 did not depolarize the cell membrane and caused a relatively short postexposure growth inhibition. These data closely parallel those previously reported for tPMP-1 against this strain set and exemplify how synthetic molecules can be engineered to reflect structure-activity relationships of functional domains in native host defense effector molecules.

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Anti-Bacterial Agents / chemical synthesis*
  • Anti-Bacterial Agents / pharmacology*
  • Antimicrobial Cationic Peptides / chemistry
  • Antimicrobial Cationic Peptides / pharmacology*
  • Bacterial Proteins / biosynthesis
  • Cell Membrane Permeability / drug effects
  • DNA, Bacterial / biosynthesis
  • Membrane Potentials / drug effects
  • Microbial Sensitivity Tests
  • Mutant Chimeric Proteins / chemical synthesis*
  • Mutant Chimeric Proteins / pharmacology*
  • Novobiocin / pharmacology
  • RNA, Bacterial / biosynthesis
  • Staphylococcus aureus / drug effects*
  • Staphylococcus aureus / metabolism
  • beta-Thromboglobulin / chemistry*
  • beta-Thromboglobulin / pharmacology*

Substances

  • Anti-Bacterial Agents
  • Antimicrobial Cationic Peptides
  • Bacterial Proteins
  • DNA, Bacterial
  • Mutant Chimeric Proteins
  • PPBP protein, human
  • RNA, Bacterial
  • beta-Thromboglobulin
  • Novobiocin