Organocatalysis "on water". Regioselective [3 + 2]-cycloaddition of nitrones and allenolates

Chem Commun (Camb). 2006 Jul 14:(26):2798-800. doi: 10.1039/b606096j.

Abstract

The first example of a regioselective and organocatalyzed 1,3-dipolar cycloaddition reaction between conjugated alkynoates and nitrones "on water" is described.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Amines / chemistry
  • Catalysis
  • Molecular Structure
  • Naphthalenes / chemistry*
  • Nitrogen Oxides / chemistry*
  • Phosphines / chemistry
  • Stereoisomerism
  • Water / chemistry*

Substances

  • Amines
  • Naphthalenes
  • Nitrogen Oxides
  • Phosphines
  • nitrones
  • Water
  • phosphine
  • allenolic acid