Synthesis of a [2]rotaxane through first- and second-sphere coordination

Barry A Blight; James A Wisner; Michael C Jennings

doi:10.1039/b610243c

Synthesis of a [2]rotaxane through first- and second-sphere coordination

Chem Commun (Camb). 2006 Nov 28:(44):4593-5. doi: 10.1039/b610243c. Epub 2006 Sep 20.

Authors

Barry A Blight¹, James A Wisner, Michael C Jennings

Affiliation

¹ Department of Chemistry, The University of Western Ontario, Chemistry Building, London, ON, CanadaN6A 5B7.

PMID: 17082853
DOI: 10.1039/b610243c

Abstract

In an effort to expand the application of a new template from interpenetrated to interlocked molecular species, we report the synthesis of a new [2]rotaxane by means of both first- and second-sphere coordination of a palladium(II) dichloride subunit.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Magnetic Resonance Spectroscopy
Models, Molecular
Molecular Conformation
Palladium / chemistry
Rotaxanes / chemical synthesis*
Rotaxanes / chemistry
Sensitivity and Specificity

Substances

Rotaxanes
Palladium
palladium chloride