NaCl-type frameworks of [M(pyrazine)2NO2]ClO4 (M = Co, Cu), the first examples containing mu(1,3)-nitrito bridges showing antiferromagnetism

Tao Liu; Yi-Hong Chen; Yan-Juan Zhang; Zhe-Ming Wang; Song Gao

doi:10.1021/ic060759x

NaCl-type frameworks of [M(pyrazine)2NO2]ClO4 (M = Co, Cu), the first examples containing mu(1,3)-nitrito bridges showing antiferromagnetism

Inorg Chem. 2006 Nov 13;45(23):9148-50. doi: 10.1021/ic060759x.

Authors

Tao Liu¹, Yi-Hong Chen, Yan-Juan Zhang, Zhe-Ming Wang, Song Gao

Affiliation

¹ Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, People's Republic of China.

PMID: 17083204
DOI: 10.1021/ic060759x

Abstract

Two new 3D NaCl-type frameworks of [M(pyrazine)2NO2]ClO4 (M = Co, Cu), consist of (4, 4) sheets of metal-pyrazine connected by mu(1,3)-nitrito, representing the first examples of mu(1,3)-nitrito bridges and exhibiting antiferromagnetism.