Abstract
cis-Dihydrodiols of anthracene and benz[a]anthracene, and acetonide derivatives of the cis-dihydrodiols of benzene, fluorobenzene, biphenyl and phenanthrene have been identified as substrates for dioxygenase enzymes, yielding the corresponding enantiopure arene bioproducts, bis(cis-dihydrodiol)s and cis-diol acetonides respectively.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Benzene Derivatives / chemical synthesis*
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Benzene Derivatives / chemistry
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Catalysis
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Crystallography, X-Ray
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Dioxygenases / chemistry*
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Hydroxylation
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Models, Molecular
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Molecular Conformation
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Naphthols / chemistry*
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Polycyclic Aromatic Hydrocarbons / chemical synthesis*
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Polycyclic Aromatic Hydrocarbons / chemistry
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Stereoisomerism
Substances
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Benzene Derivatives
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Naphthols
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Polycyclic Aromatic Hydrocarbons
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Dioxygenases