Abstract
Hexanuclear CuII-complexes of formula PPN[Cu6(micro3-O)2(micro-4-Rpz)6(micro-4-R'-3,5-Ph2pz)3] have been structurally characterized and the effect of pyrazole substituents on their two consecutive one-electron oxidation processes, leading to (possibly delocalised) mixed-valent products, has been probed by cyclic voltammetry.
Publication types
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Research Support, N.I.H., Extramural
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Research Support, U.S. Gov't, Non-P.H.S.
MeSH terms
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Copper / chemistry*
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Electrochemistry
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Magnetic Resonance Spectroscopy / methods
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Models, Molecular
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Molecular Structure
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Organometallic Compounds / chemistry*
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Oxidation-Reduction
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Pyrazoles / chemistry*
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Sensitivity and Specificity
Substances
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Organometallic Compounds
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Pyrazoles
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Copper