Abstract
The reaction of thiocarbamoyl isoselenocyanate with a carbanion gave 1-thia-6-oxa-6alambda(4)-seleno-3-azapentalene, which has a hypervalent selenium, as the major product. The by-products 3-diacylmethylidene-5-dimethylamino-3H-1,2,4-dithiazole and thiocarbamate thioanhydride were also formed.
Publication types
-
Research Support, Non-U.S. Gov't
MeSH terms
-
Bridged Bicyclo Compounds, Heterocyclic / chemical synthesis*
-
Bridged Bicyclo Compounds, Heterocyclic / chemistry
-
Magnetic Resonance Spectroscopy / methods
-
Models, Molecular
-
Molecular Structure
-
Organoselenium Compounds / chemical synthesis*
-
Organoselenium Compounds / chemistry
-
Sensitivity and Specificity
-
Stereoisomerism
-
Thiazoles / chemical synthesis*
-
Thiazoles / chemistry
-
Thiocarbamates / chemical synthesis
-
Thiocarbamates / chemistry
Substances
-
1-thia-6-oxa-6agamma(4)-seleno-3-azapentalene
-
Bridged Bicyclo Compounds, Heterocyclic
-
Organoselenium Compounds
-
Thiazoles
-
Thiocarbamates