Abstract
Sulfinimine-derived N-sulfinyl delta-amino beta-ketophosphonates are transformed via the enaminones to the phosphoryl dihydropyridones that selectively give trans-2,6-disubstituted 1,2,5,6-tetrahydropyridines on organocuprate addition and dephosphorylation.
Publication types
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Research Support, N.I.H., Extramural
MeSH terms
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Organophosphonates / chemistry*
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Piperidines / chemical synthesis*
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Pyridines / chemistry
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Pyridones / chemistry
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Quinolizines / chemical synthesis*
Substances
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Organophosphonates
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Piperidines
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Pyridines
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Pyridones
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Quinolizines
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myrtine