Hydrolysis of soybean isoflavonoid glycosides by Dalbergia beta-glucosidases

J Agric Food Chem. 2007 Mar 21;55(6):2407-12. doi: 10.1021/jf062885p. Epub 2007 Feb 21.

Abstract

Two beta-glucosidases from the legumes Dalbergia cochinchinensis and Dalbergia nigrescens were compared for their ability to hydrolyze isoflavonoid glycosides from soybean. Both D. nigrescens and D. cochinchinensis beta-glucosidases could hydrolyze conjugated soybean glycosides, but D. nigrescens beta-glucosidase hydrolyzed both conjugated and nonconjugated glycosides in crude soybean extract more rapidly. The kinetic properties Km, kcat, and kcat/Km of the Dalbergia beta-glucosidases toward conjugated isoflavonoid glycosides, determined using high-performance liquid chromatography, confirmed the higher efficiency of the D. nigrescens beta-glucosidase in hydrolyzing these substrates. The D. nigrescens beta-glucosidase could also efficiently hydrolyze isoflavone glycosides in soy flour suspensions, suggesting its application to increase free isoflavones in soy products.

Publication types

  • Comparative Study
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Dalbergia / enzymology*
  • Glycine max / chemistry*
  • Glycosides / metabolism*
  • Hydrolysis
  • Isoflavones / metabolism*
  • Species Specificity
  • beta-Glucosidase / metabolism*

Substances

  • Glycosides
  • Isoflavones
  • beta-Glucosidase