Abstract
The phosphonium borane [p-Mes(2)B(C(6)H(4))PMePh(2)](+) complexes fluoride in water containing 10% methanol with a binding constant of 1.0(+/-0.1) x 10(3) M(-1) to afford the zwitterion p-Mes(2)FB(C(6)H(4))PMePh(2).
Publication types
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Research Support, Non-U.S. Gov't
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Research Support, U.S. Gov't, Non-P.H.S.
MeSH terms
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Boranes / chemistry*
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Crystallography, X-Ray
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Fluorides / chemistry*
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Magnetic Resonance Spectroscopy
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Molecular Structure
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Solutions
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Spectrophotometry, Ultraviolet
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Water / chemistry
Substances
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Boranes
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Solutions
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Water
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Fluorides