Glycoligands and Co(II) glycocomplexes. Investigation of the variation of the sugar-scaffold on the structure and chirality measured by circular dichroism

Dalton Trans. 2007 Apr 21:(15):1473-6. doi: 10.1039/b618714e. Epub 2007 Mar 2.

Abstract

Glycoligands using various monosaccharide platforms functionalised by three 2-picolyl groups and coordinated to Co(II) through the bidentate 2-picolyl ether moieties are interesting ligands as they efficiently induce chirality at the cobalt with a fine control of the structure through the central sugar scaffold.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Circular Dichroism
  • Cobalt / chemistry*
  • Crystallography, X-Ray
  • Ligands
  • Models, Molecular
  • Monosaccharides / chemistry*
  • Organometallic Compounds / chemistry*
  • Picolinic Acids / chemistry
  • Spectrophotometry, Ultraviolet
  • Stereoisomerism

Substances

  • Ligands
  • Monosaccharides
  • Organometallic Compounds
  • Picolinic Acids
  • Cobalt