Aryl bromide/triflate selectivities reveal mechanistic divergence in palladium-catalysed couplings; the Suzuki-Miyaura anomaly

Chem Commun (Camb). 2007 May 7:(17):1742-4. doi: 10.1039/b701517h. Epub 2007 Apr 5.

Abstract

In palladium-catalysed cross-coupling reactions, the outcome of competition between aryl bromides and aryl triflates depends on the nucleophilic partner; Suzuki couplings with R-B generally follow a different pattern from other R-M species.