Combination between lacunary polyoxometalates and high-nuclear transition metal clusters under hydrothermal conditions: I. from isolated cluster to 1-D chain

Chem Commun (Camb). 2007 May 14:(18):1858-60. doi: 10.1039/b617191e. Epub 2007 Feb 15.

Abstract

The hydrothermal reactions of [A-alpha-SiW(9)O(34)](10-)/[A-alpha-PW(9)O(34)](9-) with NiCl(2) x 6H(2)O and amines yielded four unprecedented hybrid high-nuclear Ni-subsituted polyoxotungstates.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Amines / chemistry
  • Chemical Phenomena
  • Chemistry, Physical
  • Crystallization
  • Crystallography, X-Ray
  • Ligands
  • Spectrometry, Mass, Electrospray Ionization
  • Transition Elements / chemistry
  • Tungsten Compounds / chemical synthesis*

Substances

  • Amines
  • Ligands
  • Transition Elements
  • Tungsten Compounds