Synthesis of 4-iodo-3-furanones utilizing electrophile-induced tandem cyclization/1,2-migration reactions

J Org Chem. 2007 Jul 6;72(14):5435-8. doi: 10.1021/jo070695n. Epub 2007 Jun 8.

Abstract

Two protocols for the construction of 4-iodo-3-furanones through a sequence consisting of cyclization and 1,2-migration of 2-alkynyl-2-silyloxy carbonyl compounds were developed. In one, electrophilic cyclization is directly induced by N-iodosuccinimide (NIS). In the second less limited variant, AuCl3 catalyzes the tandem reaction in the presence of NIS to provide highly substituted heterocycles in moderate to excellent yields.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Alkylation
  • Cyclization
  • Electrons
  • Iodine / chemistry*
  • Lactones / chemical synthesis
  • Lactones / chemistry*
  • Molecular Structure

Substances

  • Lactones
  • Iodine