A molecular gate based on a porphyrin and a silver lock

Chem Commun (Camb). 2007 Jul 28:(28):2935-7. doi: 10.1039/b706527b. Epub 2007 Jun 20.

Abstract

A Sn(IV) metallaporphyrin bearing a 4-pyridyl group on one meso position and a handle equipped also with a pyridyl unit functions in solution as a molecular gate in the presence of silver cation: the complexation-decomplexation of Ag(I) corresponds to the opening and closing motions of the gate.