Abstract
As a part of a program for developing new efficient procedures for stereoselective glycosylation, a range of S-benzoxazolyl (SBox) glycosides have been synthesized. The mechanistic aspects of the SBox moiety activation for glycosylation via a variety of conceptually different pathways in the presence of thiophilic, electrophilic, or metal-based promoters have been investigated.
Publication types
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Research Support, N.I.H., Extramural
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Research Support, Non-U.S. Gov't
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Research Support, U.S. Gov't, Non-P.H.S.
MeSH terms
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Alkylation
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Benzoxazoles / chemistry*
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Catalysis
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Crystallography, X-Ray
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Glycosides / chemical synthesis
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Glycosides / chemistry*
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Ions / chemistry
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Metals / chemistry
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Models, Molecular
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Molecular Structure
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Protons
Substances
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Benzoxazoles
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Glycosides
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Ions
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Metals
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Protons