Metal-ligand interplay in strongly correlated oxides: a parametrized phase diagram for pressure-induced spin transitions

Phys Rev Lett. 2007 May 11;98(19):196404. doi: 10.1103/PhysRevLett.98.196404. Epub 2007 May 9.

Abstract

We investigate the magnetic properties of archetypal transition-metal oxides MnO, FeO, CoO, and NiO under very high pressure by x-ray emission spectroscopy at the Kbeta line. We observe a strong modification of the magnetism in the megabar range in all the samples except NiO. The results are analyzed within a multiplet approach including charge-transfer effects. The spectral changes are well accounted for by changes of the ligand field acting on the d electrons and allows us to extract the d-hybridization strength, O-2p bandwidth and ionic crystal field across the magnetic transition. This approach allows first-hand insight into the mechanism of the pressure-induced spin transition.

Publication types

  • Research Support, Non-U.S. Gov't