Configurational assignment of N-arylsulfonylimines of alpha-polychloroaldehydes

Leonid B Krivdin; Kirill A Chernyshev; Gulnur N Rosentsveig; Irina V Ushakova; Igor B Rosentsveig; Galina G Levkovskaya

doi:10.1002/mrc.2070

Configurational assignment of N-arylsulfonylimines of alpha-polychloroaldehydes

Magn Reson Chem. 2007 Nov;45(11):980-4. doi: 10.1002/mrc.2070.

Authors

Leonid B Krivdin¹, Kirill A Chernyshev, Gulnur N Rosentsveig, Irina V Ushakova, Igor B Rosentsveig, Galina G Levkovskaya

Affiliation

¹ A. E. Favorsky Institute of Chemistry, Irkutsk, Siberian Branch of the Russian Academy of Sciences, Favorsky St. 1, 664033 Irkutsk, Russia. [email protected]

PMID: 17876855
DOI: 10.1002/mrc.2070

Abstract

Configurational assignment of seven synthesized N-arylsulfonylimines of alpha-polychloroaldehydes has been carried out by means of experimental measurements and high-level ab initio calculations of their (13)C--(13)C, (13)C--(1)H and (15)N--(1)H spin-spin coupling constants. The title compounds were shown to exist in solution solely in the form of E isomers, in line with thermodynamic reasoning.