A versatile electronic hole in one-electron oxidized NiIIbis-salicylidene phenylenediamine complexes

Chem Commun (Camb). 2007 Nov 21:(43):4462-4. doi: 10.1039/b710027b. Epub 2007 Aug 28.

Abstract

The nickel complexes 1(+)-3(+) exhibit a delocalized radical character, the extent of which depends on the electronic properties of the phenolate para-substituent.

MeSH terms

  • Electrons
  • Models, Molecular
  • Nickel / chemistry*
  • Organometallic Compounds / chemistry*
  • Oxidation-Reduction
  • Salicylates / chemistry*

Substances

  • Organometallic Compounds
  • Salicylates
  • salophen
  • Nickel