Isolation and characterization of a serine proteinase with thrombin-like activity from the venom of the snake Bothrops asper

Braz J Med Biol Res. 2008 Jan;41(1):12-7. doi: 10.1590/s0100-879x2006005000189. Epub 2007 Dec 17.

Abstract

A serine proteinase with thrombin-like activity was isolated from the venom of the Central American pit viper Bothrops asper. Isolation was performed by a combination of affinity chromatography on aminobenzamidine-Sepharose and ion-exchange chromatography on DEAE-Sepharose. The enzyme accounts for approximately 0.13% of the venom dry weight and has a molecular mass of 32 kDa as determined by SDS-PAGE, and of 27 kDa as determined by MALDI-TOF mass spectrometry. Its partial amino acid sequence shows high identity with snake venom serine proteinases and a complete identity with a cDNA clone previously sequenced from this species. The N-terminal sequence of the enzyme is VIGGDECNINEHRSLVVLFXSSGFL CAGTLVQDEWVLTAANCDSKNFQ. The enzyme induces clotting of plasma (minimum coagulant dose = 4.1 microg) and fibrinogen (minimum coagulant dose = 4.2 microg) in vitro, and promotes defibrin(ogen)ation in vivo (minimum defibrin(ogen)ating dose = 1.0 microg). In addition, when injected intravenously in mice at doses of 5 and 10 microg, it induces a series of behavioral changes, i.e., loss of the righting reflex, opisthotonus, and intermittent rotations over the long axis of the body, which closely resemble the ;gyroxin-like' effect induced by other thrombin-like enzymes from snake venoms.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Amino Acid Sequence
  • Animals
  • Antivenins / therapeutic use
  • Blood Coagulation* / drug effects
  • Bothrops*
  • Chromatography, Agarose
  • Chromatography, Ion Exchange
  • Coagulants / administration & dosage
  • Coagulants / isolation & purification*
  • Coagulants / pharmacology
  • Costa Rica
  • Crotalid Venoms / enzymology*
  • Drug Evaluation, Preclinical
  • Fibrinogen / metabolism
  • Mice
  • Serine Endopeptidases / chemistry
  • Serine Endopeptidases / genetics
  • Serine Endopeptidases / isolation & purification*
  • Serine Endopeptidases / pharmacology
  • Snake Bites / physiopathology
  • Thrombin / chemistry

Substances

  • Antivenins
  • Coagulants
  • Crotalid Venoms
  • Fibrinogen
  • Serine Endopeptidases
  • Thrombin