Nanomechanical characterization of polyaniline coated tobacco mosaic virus nanotubes

J Biomed Mater Res A. 2008 Oct;87(1):8-14. doi: 10.1002/jbm.a.31617.

Abstract

Mechanical properties of polyaniline (PANI) coated self-assembled tobacco mosaic virus (TMV) nanotubes were measured by nanoindentation with an atomic force microscope (AFM) probe. The elastic modulus of PANI/TMV core-shell biocomposite tubes (outer diameter: 19 nm, inner diameter: 4 nm, PANI coating thickness: 0.5 nm) was measured from the AFM force-displacement curves. Structural characteristics of the PANI coating, TMV tube, and their interface were studied by comparing the mechanical properties of individual constituent materials. Results showed that coating with a thin layer of PANI can change the physical and chemical properties of TMV nanotubes. The deformation behavior of such core-shell biocomposite tubes is discussed in conjunction with the obtained AFM force-displacement curves, van der Waals interaction between PANI and TMV, and mechanical properties of individual constituent materials.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Aniline Compounds / chemistry*
  • Elasticity
  • Materials Testing
  • Microscopy, Atomic Force
  • Models, Molecular
  • Nanotechnology
  • Nanotubes / chemistry*
  • Nanotubes / ultrastructure
  • Stress, Mechanical
  • Surface Properties
  • Tobacco Mosaic Virus / chemistry
  • Tobacco Mosaic Virus / ultrastructure*

Substances

  • Aniline Compounds
  • polyaniline