A multicomponent synthesis of triazinane diones

J Org Chem. 2008 Jan 18;73(2):719-22. doi: 10.1021/jo701973d. Epub 2007 Dec 21.

Abstract

An efficient, one-pot synthetic protocol toward triazinane diones, a rather unexplored class of heterocyclic scaffolds combining phosphonates, nitriles, aldehydes, and isocyanates is described. The optimization of the reaction, synthesis of a small library of different triazinane diones, as well as alternative routes toward the triazinane dione scaffold are discussed.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Aldehydes / chemistry
  • Cyclization
  • Isocyanates / chemistry
  • Ketones / chemical synthesis*
  • Ketones / chemistry
  • Molecular Structure
  • Nitriles / chemistry
  • Organophosphonates / chemistry
  • Small Molecule Libraries
  • Stereoisomerism
  • Triazines / chemical synthesis*
  • Triazines / chemistry
  • Urea / analogs & derivatives
  • Urea / chemical synthesis*
  • Urea / chemistry

Substances

  • Aldehydes
  • Isocyanates
  • Ketones
  • Nitriles
  • Organophosphonates
  • Small Molecule Libraries
  • Triazines
  • Urea