Effect of prochloraz fungicide on biotransformation enzymes and oxidative stress parameters in three-spined stickleback (Gasterosteus aculeatus L.)

J Environ Sci Health B. 2008 Jan;43(1):65-70. doi: 10.1080/03601230701735151.

Abstract

The aim of this study was to characterize biomarker responses in three-spined sticklebacks exposed to prochloraz (Pcz). For this purpose, adult sticklebacks were exposed for 2 weeks to prochloraz at 0, 10, 50, 100 and 500 microg/L prior to one week of depuration in clean water. At days 7, 14 and 21, several hepatic biomarkers were measured including 7-ethoxyresorufin-O-deethylase (EROD), glutathione-S-transferase (GST), glutathione peroxidase (GPx), catalase (CAT), total glutathione (GSH) content and thiobarbituric acid reactive substances (TBARS). Pcz induced a transient increase of antioxidant enzymes and a depletion of glutathione content during the first 7 days of exposure. This study showed that EROD activity and antioxidants were disrupted in a transient manner. GST was rapidly induced in a dose-dependent manner and this induction was persistent and observed also after depuration. GST appeared as a valuable biomarker to assess the exposure to Pcz.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animals
  • Biomarkers / analysis
  • Biomarkers / metabolism
  • Catalase / analysis
  • Catalase / metabolism
  • Cytochrome P-450 CYP1A1 / analysis
  • Cytochrome P-450 CYP1A1 / metabolism
  • Dose-Response Relationship, Drug
  • Environmental Monitoring / methods
  • Fungicides, Industrial / toxicity*
  • Glutathione / analysis
  • Glutathione / metabolism
  • Glutathione Peroxidase / analysis
  • Glutathione Peroxidase / metabolism
  • Glutathione Transferase / analysis
  • Glutathione Transferase / metabolism
  • Imidazoles / toxicity*
  • Liver / enzymology*
  • Liver / metabolism
  • Oxidative Stress / drug effects*
  • Smegmamorpha / growth & development*
  • Thiobarbituric Acid Reactive Substances / analysis
  • Thiobarbituric Acid Reactive Substances / metabolism
  • Time Factors
  • Water Pollutants, Chemical / toxicity

Substances

  • Biomarkers
  • Fungicides, Industrial
  • Imidazoles
  • Thiobarbituric Acid Reactive Substances
  • Water Pollutants, Chemical
  • prochloraz
  • Catalase
  • Glutathione Peroxidase
  • Cytochrome P-450 CYP1A1
  • Glutathione Transferase
  • Glutathione