Azatricarbaborane 7-t-Bu-arachno-7,1,5,12-NC3B8H12 and Parent Tricarbaboranes nido-[5,6,9-C3B7H10]- and -5,6,9-C3B7H11

Josef Holub; Mario Bakardjiev; Drahomír Hnyk; Ivana Císarova; Bohumil Stíbr

doi:10.1021/ic701568r

Azatricarbaborane 7-t-Bu-arachno-7,1,5,12-NC3B8H12 and Parent Tricarbaboranes nido-[5,6,9-C3B7H10]- and -5,6,9-C3B7H11

Inorg Chem. 2008 Feb 4;47(3):760-2. doi: 10.1021/ic701568r. Epub 2008 Jan 5.

Authors

Josef Holub¹, Mario Bakardjiev, Drahomír Hnyk, Ivana Císarova, Bohumil Stíbr

Affiliation

¹ Institute of Inorganic Chemistry, Academy od Sciences of the Czech Republic, CZ-250 68 ReZ, Czech Republic.

PMID: 18177035
DOI: 10.1021/ic701568r

Abstract

The neutral azatricarbaborane 7-t-Bu-arachno-7,1,5,12-NC(3)B(8)H(12), isolated as a side product (yield 2%) from the new synthesis of 7-t-BuNH2-nido-7,8,9-C(3)B(8)H(10) (yield 70%), can be easily converted to the first parent representatives of the 10-vertex nido family of tricarbaboranes, [5,6,9-C(3)B(7)H(10)]- and 5,6,9-C(3)B(7)H(11).