Total synthesis of (+)-aquaticol by biomimetic phenol dearomatization: double diastereofacial differentiation in the diels-alder dimerization of orthoquinols with a c(2)-symmetric transition state

Angew Chem Int Ed Engl. 2008;47(4):628. doi: 10.1002/anie.200890007.
No abstract available

MeSH terms

  • Biomimetics*
  • Cyclization
  • Dimerization
  • Hydroquinones / chemistry*
  • Models, Molecular
  • Molecular Conformation
  • Oxidation-Reduction
  • Phenols / chemistry*
  • Stereoisomerism
  • Triterpenes / chemical synthesis*
  • Triterpenes / chemistry

Substances

  • Hydroquinones
  • Phenols
  • Triterpenes
  • aquaticol