Origins of differences in reactivities of alkenes, alkynes, and allenes in [Rh(CO)2Cl]2-catalyzed (5 + 2) cycloaddition reactions with vinylcyclopropanes

J Am Chem Soc. 2008 Feb 27;130(8):2378-9. doi: 10.1021/ja076444d. Epub 2008 Feb 2.
No abstract available

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Alkenes / chemistry*
  • Alkynes / chemistry*
  • Bridged Bicyclo Compounds, Heterocyclic / chemical synthesis*
  • Bridged Bicyclo Compounds, Heterocyclic / chemistry
  • Catalysis
  • Cyclization
  • Cyclopropanes / chemistry*
  • Models, Chemical
  • Molecular Structure
  • Rhodium / chemistry*
  • Stereoisomerism
  • Vinyl Compounds / chemistry*

Substances

  • Alkenes
  • Alkynes
  • Bridged Bicyclo Compounds, Heterocyclic
  • Cyclopropanes
  • Vinyl Compounds
  • Rhodium