Abstract
The synthesis of five fused-bicyclic medium-ring lactones carrying identical ring-fusion to that in the polyether toxins is described using an enolate hydroxylation, intramolecular hydrosilation, Claisen rearrangement sequence.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Bridged Bicyclo Compounds, Heterocyclic / chemical synthesis*
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Bridged Bicyclo Compounds, Heterocyclic / chemistry
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Crystallography, X-Ray
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Hydroxylation
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Lactones / chemical synthesis*
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Lactones / chemistry
Substances
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Bridged Bicyclo Compounds, Heterocyclic
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Lactones