The principal refractive indices and the thermal refractive-index coefficients of 7.5-mol.% Nb:KTiOPO(4) crystal were measured by autocollimation for wavelengths of 0.53975, 0.6328, 1.0795, and 1.3414 microm from room temperature to 143 degrees C. The Sellmeier equations at room temperature were obtained and used to calculate the optimal phase-matched angles for 1.0642 and 1.0795 microm. The calculated and experimental values are in good agreement.