Dendritic crystal growth, differential circular scattering, and the origin of biomolecular homochirality

Chirality. 2008 Sep;20(9):973-7. doi: 10.1002/chir.20539.

Abstract

Phthalic acid rapidly crystallizing in thin aqueous films is deposited radially and rhythmically as dendritic banded spherulites that have heterochiral meso-textures in hemi-circles. The chiral fields differentially scatter left and right circularly polarized light. A scenario for chiral amplification and the origin of biomolecular homochirality is thus proposed that combines the influences of crystals and light.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Crystallization
  • Models, Biological*
  • Stereoisomerism