Chemically modified oligonucleotides with efficient RNase H response

Bioorg Med Chem Lett. 2008 Apr 1;18(7):2296-300. doi: 10.1016/j.bmcl.2008.03.004. Epub 2008 Mar 6.

Abstract

Ten different chemically modified nucleosides were incorporated into short DNA strands (chimeric oligonucleotides ON3-ON12 and ON15-ON24) and then tested for their capacity to mediate RNAse H cleavage of the complementary RNA strand. The modifications were placed at two central positions directly in the RNase H cleaving region. The RNA strand of duplexes with ON3, ON5 and ON12 were cleaved more efficiently than the RNA strand of the DNA:RNA control duplex. There seems to be no correlation between the thermal stability between the duplexes and RNase H cleavage.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Base Sequence
  • Binding Sites
  • DNA / chemistry
  • DNA / metabolism
  • Nucleic Acid Conformation
  • Oligonucleotides* / chemistry
  • Oligonucleotides* / metabolism
  • RNA* / chemistry
  • RNA* / metabolism
  • Ribonuclease H / chemistry
  • Ribonuclease H / metabolism*
  • Substrate Specificity

Substances

  • Oligonucleotides
  • RNA
  • DNA
  • Ribonuclease H