Concerning the synthesis of the tedanolide C(13)-C(23) fragment via anti-aldol reaction

Org Lett. 2008 May 15;10(10):2059-62. doi: 10.1021/ol800546g. Epub 2008 Apr 19.

Abstract

Synthesis of C(13)-C(23) aldehyde 4, an important intermediate in a planned total synthesis of tedanolide, is described. The stereoselectivity of the key anti-aldol reaction of aldehyde 5 and ketone 6 (en route to 4) perfectly tracks the enantiomeric purity of 5. It is demonstrated that aldehyde 24, a precursor of 5, undergoes facile epimerization during a Swern oxidation and stabilized ylide olefination sequence.

Publication types

  • Research Support, N.I.H., Extramural

MeSH terms

  • Aldehydes / chemical synthesis*
  • Aldehydes / chemistry
  • Ketones / chemical synthesis
  • Ketones / chemistry
  • Lactones / chemical synthesis
  • Lactones / chemistry
  • Macrolides
  • Molecular Structure
  • Stereoisomerism

Substances

  • Aldehydes
  • Ketones
  • Lactones
  • Macrolides
  • tedanolide