Two-photon absorption enhancement induced by aggregation due to intermolecular hydrogen bonding in V-shaped 2-hydroxypyrimidine derivatives

Zijun Liu; Pin Shao; Zhenli Huang; Bo Liu; Tao Chen; Jingui Qin

doi:10.1039/b718147g

Two-photon absorption enhancement induced by aggregation due to intermolecular hydrogen bonding in V-shaped 2-hydroxypyrimidine derivatives

Chem Commun (Camb). 2008 May 21:(19):2260-2. doi: 10.1039/b718147g. Epub 2008 Mar 11.

Authors

Zijun Liu¹, Pin Shao, Zhenli Huang, Bo Liu, Tao Chen, Jingui Qin

Affiliation

¹ Hubei Key Laboratory on Organic and Polymeric Opto-electronic Materials, Department of Chemistry, Wuhan University, Wuhan 430072, China.

PMID: 18463759
DOI: 10.1039/b718147g

Abstract

The aggregation of V-shaped hydroxypyrimidine derivatives is formed through an intermolecular hydrogen bond in chloroform that cannot form a hydrogen bond with the solute, giving rise to a large enhancement of the two-photon absorption and two-photon induced fluorescence.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Absorption
Fluorescence
Hydrogen Bonding
Magnetic Resonance Spectroscopy / methods
Molecular Conformation
Photons
Pyrimidines / chemistry*
Spectrophotometry, Ultraviolet

Substances

Pyrimidines