A comparative study of AgX (X = Cl(-), Br(-), I(-) and N(3)(-)) solid-phase reactors for flow-injection determination of cyanide in electroplating wastewater

Anal Sci. 2008 May;24(5):669-72. doi: 10.2116/analsci.24.669.

Abstract

In this study, a rapid flow injection-flame atomic absorption spectrometry for cyanide detection was developed. Different AgX (where X is Cl(-), Br(-), I(-) and N(3)(-)) solid-phase reagents (SPR) were tested for indirect determination of cyanide. In a single-line FIA system, the cyanide was allowed to react with AgX SPR, which in turn changed Ag ions in AgX to silver cyanide complexes in a sodium hydroxide carrier stream. The eluent containing the analyte as silver cyanide complexes was measured by FAAS. The calibration curve was linear up to 30 mg l(-1) with a detection limit of 0.05 mg l(-1) for cyanides. The sampling rate and the relative standard deviation were <1.09% and >200 h(-1), respectively. The method was applied to the determination of cyanide in electroplating wastewater.

Publication types

  • Comparative Study
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Cyanides / analysis*
  • Cyanides / chemistry
  • Electroplating
  • Flow Injection Analysis / instrumentation
  • Flow Injection Analysis / methods*
  • Halogens / chemistry*
  • Nitrogen Compounds / analysis*
  • Nitrogen Compounds / chemistry
  • Silver Compounds / analysis*
  • Silver Compounds / chemistry
  • Solid Phase Extraction / instrumentation
  • Solid Phase Extraction / methods*
  • Water Pollutants, Chemical / analysis*
  • Water Pollutants, Chemical / chemistry

Substances

  • Cyanides
  • Halogens
  • Nitrogen Compounds
  • Silver Compounds
  • Water Pollutants, Chemical