Abstract
The use of manganese(III) acetate in combination with copper(II) triflate allows the synthesis of [3.3.0]-bicyclic gamma-lactones from 4-pentenylmalonates in excellent yields.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Acetates / chemistry
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Bridged Bicyclo Compounds, Heterocyclic / chemical synthesis*
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Bridged Bicyclo Compounds, Heterocyclic / chemistry
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Copper / chemistry
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Cyclization
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Cyclopentanes / chemical synthesis
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Cyclopentanes / chemistry
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Free Radicals / chemistry
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Lactones / chemical synthesis*
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Lactones / chemistry
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Malonates / chemistry
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Mesylates / chemistry
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Molecular Structure
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Organometallic Compounds / chemistry
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Oxidation-Reduction
Substances
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Acetates
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Bridged Bicyclo Compounds, Heterocyclic
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Cyclopentanes
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Free Radicals
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Lactones
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Malonates
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Mesylates
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Organometallic Compounds
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manganese(III) acetate dihydrate
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Copper
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trifluoromethanesulfonic acid