Effect of different wood pretreatments on the sorption-desorption of linuron and metalaxyl by woods

J Agric Food Chem. 2008 Aug 27;56(16):7339-46. doi: 10.1021/jf800980w. Epub 2008 Jul 19.

Abstract

The sorption-desorption of two different pesticides, linuron and metalaxyl, by woods was studied. Sorbent/solution ratio and sorption kinetics were also determined. Untreated wood and water, NaOH, HCl, and octadecyltrimethylammonium bromide (ODTMA) treated pine (softwood) and oak (hardwood) were used as sorbents. Linuron and metalaxyl were sorbed by untreated woods up to 80 and 40%, respectively, in a short time when the sorbent/solution ratio of 1:10 was used. Sorption of pesticides was significantly higher by pine, having higher lignin content, than by oak. Freundlich sorption constants (K(f)) were 96.2 and 74.4 (linuron) and 8.28 and 4.95 (metalaxyl) for untreated pine and oak woods and increased 1.04-2.35-fold (linuron) and 1.33-2.17-fold (metalaxyl) when woods were treated. The sorption was higher by HCl- and ODTMA-treated woods. Additionally, Freundlich desorption constants also indicated greater sorption irreversibility of both pesticides for treated woods than for untreated woods. The results revealed wood residues as a promising, low-cost, and environmentally friendly material to immobilize pesticides in soils, preventing water contamination. Wood treatments aimed at removing soluble wood extracts or at modifying wood chemical structure could increase their sorption capacity.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Adsorption
  • Alanine / analogs & derivatives*
  • Alanine / chemistry
  • Alkanes / pharmacology
  • Fungicides, Industrial / chemistry*
  • Herbicides / chemistry*
  • Hydrochloric Acid / pharmacology
  • Kinetics
  • Linuron / chemistry*
  • Pinus / chemistry
  • Quaternary Ammonium Compounds / pharmacology
  • Quercus / chemistry
  • Sodium Hydroxide / pharmacology
  • Solutions
  • Water Pollution / prevention & control
  • Wood / chemistry*
  • Wood / drug effects

Substances

  • Alkanes
  • Fungicides, Industrial
  • Herbicides
  • Quaternary Ammonium Compounds
  • Solutions
  • octadecyltrimethylammonium bromide
  • Linuron
  • metalaxyl
  • Sodium Hydroxide
  • Alanine
  • Hydrochloric Acid