Abstract
An unusual dinuclear Ir(I) complex bridged by two N-heterocyclic biscarbene ligands, forming a 20-membered, figure-of-eight dimetallacycle, and new CNHCCCNHC pincer complexes of Ir(III) have been obtained directly from the bis(imidazolium) precursors and [Ir(micro-Cl)(cod)]2.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Cations
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Heterocyclic Compounds / chemistry*
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Imidazoles / chemistry*
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Iridium / chemistry*
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Ligands
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Methane / analogs & derivatives*
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Methane / chemistry
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Molecular Structure
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Organometallic Compounds / chemical synthesis*
Substances
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Cations
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Heterocyclic Compounds
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Imidazoles
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Ligands
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Organometallic Compounds
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carbene
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Iridium
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Methane