Spirastrellolide B: the synthesis of southern (C9-C25) region

Org Lett. 2008 Oct 2;10(19):4355-7. doi: 10.1021/ol801771s. Epub 2008 Sep 3.

Abstract

A combination of "chiron" and "asymmetric" approaches is utilized to construct the southern (C 9-C 25) region of marine natural product spirastrellolide B. The key functionalities are derived from d-glucose and Sharpless asymmetric epoxidation and dihydroxylation.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Biological Products / chemical synthesis
  • Biological Products / chemistry
  • Macrolides / chemical synthesis*
  • Macrolides / chemistry
  • Spiro Compounds / chemical synthesis*
  • Spiro Compounds / chemistry

Substances

  • Biological Products
  • Macrolides
  • Spiro Compounds
  • spirastrellolide B
  • spirastrellolide C