Combination of aptamer with gold nanoparticles for electrochemical signal amplification: application to sensitive detection of platelet-derived growth factor

Biosens Bioelectron. 2009 Feb 15;24(6):1598-602. doi: 10.1016/j.bios.2008.08.030. Epub 2008 Aug 27.

Abstract

In this paper, we report a novel electrochemical detection approach for platelet-derived growth factor (PDGF) via "sandwich" structure and gold nanoparticles (Au-NPs) mediated amplification technique. The "sandwich" structure is fabricated based on the fact that PDGF has two aptamer-binding sites, which makes it possible for one PDGF molecule to connect with two aptamers simultaneously. It is found that this electrochemical system with "sandwich" structure and Au-NPs can significantly amplify the signal of electrochemical probe [Ru(NH(3))(5)Cl](2+) for PDGF detection, and thus increase the detection sensitivity significantly. As a result, this PDGF detection approach obtains an extraordinarily low detection limit of 1 x 10(-14)M for purified samples, 1 x 10(-12)M for contaminated-ridden samples or undiluted blood serum. This detection approach can also exhibit good stability and excellent specificity.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Aptamers, Nucleotide / chemistry*
  • Biosensing Techniques / instrumentation*
  • Electrochemistry / instrumentation*
  • Electrochemistry / methods
  • Equipment Design
  • Equipment Failure Analysis
  • Gold / chemistry*
  • Microchemistry / instrumentation*
  • Microchemistry / methods
  • Nanoparticles / chemistry*
  • Nanoparticles / ultrastructure
  • Nanotechnology / instrumentation*
  • Platelet-Derived Growth Factor / analysis*
  • Reproducibility of Results
  • Sensitivity and Specificity

Substances

  • Aptamers, Nucleotide
  • Platelet-Derived Growth Factor
  • Gold