Metal-free one-pot oxidative amidation of aldoses with functionalized amines

J Org Chem. 2008 Nov 7;73(21):8647-50. doi: 10.1021/jo801626v. Epub 2008 Oct 8.

Abstract

Metal-free one-pot oxidative amidation of aldoses with functionalized amines using iodine provides a rapid access to functionalized aldonamides. The main advantage of this approach relies on the fact that aldehyde oxidation and C-N bond formation are performed in a single synthetic operation.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Amides / chemical synthesis*
  • Amines / chemistry*
  • Carbohydrates / chemistry*
  • Oxygen

Substances

  • Amides
  • Amines
  • Carbohydrates
  • Oxygen