Spontaneous formation of vertical magnetic-metal-nanorod arrays during plasma-enhanced atomic layer deposition

Small. 2008 Dec;4(12):2247-54. doi: 10.1002/smll.200801074.

Abstract

A novel fabrication method of Co and Ni metal nanorods (NRs) without catalyst or template, based on the spontaneous formation of NRs during plasma-enhanced atomic layer deposition (PE-ALD) is developed. Pure Co and Ni NRs 9-10 nm in diameter are synthesized on SiO(2) and Si substrates by using metal-organic precursors and an NH(3) plasma mixed with a suitable amount of SiH(4) as a reactant. The lengths of the NRs are controlled on the nanometer scale by changing the number of PE-ALD growth cycles. Superconducting quantum interference device magnetometer measurements confirm the magnetic anisotropy of Co NRs caused by shape anisotropy.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Metal Nanoparticles / chemistry
  • Microarray Analysis
  • Microscopy, Electron, Transmission
  • Nanotechnology / instrumentation
  • Nanotubes / chemistry*
  • Surface Properties